| 1. | Onii-sama, watashi no shimobe ni narinasai (おにいさま、私のシモベになりなさい♡) Big Brother, Be My Slave |
| 2. | Go-shujin-sama to oyobinasai (御主人様とお呼びなさい) Call Me Mistress |
| 3. | Onii-sama, atashi to issho ni kurashite kudasai ne (おにいさま、私といっしょに暮らしてくださいね) Big Brother, Let\'s Live Together |
| 4. | Oniisama, ...KISU shitaku natsayta (おにいさま、・・・キスしたくなっちゃた) Big Brother, I Feel Like Kissing |
| 5. | Oniisama, Furu Furu Furu Muun (おにいさま、ふるふるふるむーん) It\'s a Full, Full Moon |
| 6. | Oniisama to Kyoto de...uhu<3wakuwaku<3 (おにいさまと京都で…うふ<3わくわく<3) Heart Throbs in Kyoto |
| 7. | ...Datte hoshikattanda mon (……だって欲しかったんだもん) Well, I Wanted It... |
| 8. | Okaasama ga kitekureta! ureshii (母様がきてくれた！うれしい) Mother Came to See Me! Happy! |
| 9. | Oniisama, watashi wo yume kara dasukete...onegai (おにいさま、私を夢から助けて…おねがい) Save Me From This Dream |
| 10. | Yurusanai...hajimete no shimobe no kuse ni (ゆるさない…初めてのシモベのくせに) You\'re My Slave and I Won\'t Forgive You |
| 11. | Oniisama, ansei ni shitenakya dame (おにいさま、安静にしてなきゃダメ) Big Brother, Get Some Rest! |
| 12. | Yurusanai no, aitsu dake wa...! (ゆるせないの、あいつだけは…！) I\'ll Never Forgive Him! |
| 13. | Onii-sama, minna de hakushaku o taoshimashou ne (おにいさま、みんなで伯爵を倒しましょうね) Let\'s Defeat the Count |
| 14. | Oniisama to isshoni...osanpo shitai desu (おにいさまといっしょに…お散歩したいです) Big Brother, Will You Walk With Me? |
| 15. | Oniisama, \"sekinin\" tottekudasai ne (おにいさま、“せきにん”とってくださいね) It\'s More Than a Responsibility! |
| 16. | Oniisama, doushitemo furufurudou no nekomimi manju jyanakucha dame nandesu (おにいさま、どうしてもふるふる堂のネコミミ饅頭じゃなくちゃだめなんです) I Have to Eat Cat Ear Buns! |
| 17. | Oniisama, nande konna koto ni naru wake!? (おにいさま、なんでこんなことになるわけ!?) Big Brother, Why Is This Happening? |
| 18. | Yaho~ Haiho~ Ima, aini ikimasune (ヤッホーハイホー 今、会いに行きますね) Yahoo! I\'ll See You Soon! |
| 19. | Oyama no Hi - Yukemuri no Saru - Neko no Hige... de, Anta-tachi Dare? (お山の日 湯けむりのサル ねこのヒゲ …で、あんたたち誰？) Day on the Mountain, Monkey in the Spa, the Cat\'s Whiskers... And Who Are You? |
| 20. | Ojii-sama, Doushite Sonna Kakkou Shiteru n desu ka? (おじいさま、どーしてそんな格好してるんですか？) Grandfather, Why Are You Dressed Like That? |
| 21. | Oniisama, sorette doko no chihou no temari uta? (おにいさま、それってどこの地方の手まり唄？) Big Brother, Where Is This Nursery Rhyme From? |
| 22. | Oniisama, sonna hito dattan desuka!? (おにいさま、そんな人だったんですか!?) I Didn\'t Know You Were Like That! |
| 23. | Oniisama, watashitte sonna ni hen desuka? (おにいさま、わたしってそんなにヘンですか？) Big Brother, Am I That Scary? |
| 24. | Sayonara, Oniisama...watashi, honto ni kaecchauyo? Kaecchauyo? (サヨナラ、おにいさま……私、ホントに帰っちゃうよ？ 帰っちゃうよ？) Good-Bye Big Brother... I\'m Going Back? I\'m Really Going Back? |
| 25. | Oniisama, saishuukai da soudesuyo ♡ Zutto watshi no shimobe de itekudasai ne ♡♡♡ (おにいさま、最終回だそうですよ♡ ずっと私のシモベでいてくださいね♡♡♡) Big Brother, They Say It\'s The End! Will You Always Be My Slave? |
| 26. | Onii-Sama, wavering wavering sparkling sparkiling drifting. What\'s this? (おにいさま、ゆらゆらきらきらどんぶらこ これって、なーんだ？) Up and Down, In the Sun, Floating Away... What Is It? |
| OP: | \"Neko Mimi Mode\" - Dimitri from Paris \"Tsukuyomi Mode\" - Dimitri from Paris |
| ED: | \"Kanashii Yokan\" - Marianne Amplifier feat. Yuka \"Nami no Toriko ni naru you ni\" - Noriko Owaga \"Pressentiment Triste\" - Marianne Amplifier feat. Yuka \"Neko Mimi Mode\" - Dimitri from Paris |
Saito Chiwa   : | Hazuki/Luna |
| Kamiya Hiroshi : | Morioka Kouhei |
| Kadowaki Mai : | Mido Hikaru |
| Matsuki Miyu : | Mido Kaoru |
| Mugihito : | Mido Ryuhei |
| Sakurai Takahiro : | Mido Seiji |
| Yamazaki Vanilla : | Haiji |
| Kakazu Yumi : | Elfriede |
| Ishige Sawa : | Art |
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